[1]陈欢,范东斌,杨昇.三唑基豆粕胶黏剂的防霉交联剂合成及应用[J].森林与环境学报,2020,40(06):662-666.[doi:10.13324/j.cnki.jfcf.2020.06.014]
 CHEN Huan,FAN Dongbin,YANG Sheng.Synthesis and application of the triazolyl mold-proof cross-linking agent for soybean meal adhesive[J].,2020,40(06):662-666.[doi:10.13324/j.cnki.jfcf.2020.06.014]
点击复制

三唑基豆粕胶黏剂的防霉交联剂合成及应用()
分享到:

《森林与环境学报》[ISSN:2096-0018/CN:35-1327/S]

卷:
40卷
期数:
2020年06期
页码:
662-666
栏目:
出版日期:
2020-11-15

文章信息/Info

Title:
Synthesis and application of the triazolyl mold-proof cross-linking agent for soybean meal adhesive
作者:
陈欢 范东斌 杨昇
中国林业科学研究院木材工业研究所, 北京 100091
Author(s):
CHEN Huan FAN Dongbin YANG Sheng
Research Institute of Wood Industry, Chinese Academy of Forestry, Beijing 100091, China
关键词:
豆粕胶黏剂三唑基团接枝防霉交联剂
Keywords:
soybean meal adhesivetriazolegraftanti-moldcross-linking agent
分类号:
TQ432
DOI:
10.13324/j.cnki.jfcf.2020.06.014
摘要:
为有效提升豆粕胶黏剂中防霉剂与交联剂兼容性,在保证交联剂性能不变的前提下有效提升豆粕胶黏剂防霉性能,提出了通过接枝反应将具有防霉性能的三唑官能团引入水性环氧聚合物(交联剂)分子结构中,并与微量水溶性防霉剂复合,制备兼具胶合性和防霉性的交联剂。对合成产物分子结构及防霉体系性能检测,结果表明:三唑基团可有效接枝到水性环氧聚合物分子结构中,合成产物与微量水溶性防霉剂复合可达到理想的防霉效果;当新型交联剂用量为4.5%时,豆粕胶黏剂胶合强度为0.78 MPa,满足国家标准GB/T9846—2015规定的Ⅱ类胶合板要求。
Abstract:
Soybean meal adhesive is easily harmed by mildew, and therefore requires not only excellent bonding strength, but also stable mildew-esistance. However, the poor compatibility of mildew preventives with the cross-linking agent makes it hard to improve the mold inhibition of soybean meal adhesive without harming the performance of the cross-linking agent. In this study, a triazole group was introduced into the waterborne epoxy polymer through graft reaction. The product was compounded with a small quantity of water-soluble anti-mildew agents to prepare the crosslinking system with ideal mildew resistance and increased bonding strength. Our results show that the triazole group could be grafted into the structure of the waterborne epoxy polymer. The bonding strength of the prepared plywood reached 0.78 MPa when the dosage of new cross-linking agent was 4.5%, which met the national standard for type Ⅱ plywood.

参考文献/References:

[1] 郝秀,范东斌.环氧化合物改性大豆蛋白胶黏剂制备工艺与性能研究[J].林产工业,2019,56(11):48-51,64.
[2] 高强,刘峥,李建章.人造板用大豆蛋白胶黏剂研究进展[J].林业工程学报,2020,5(2):1-11.
[3] 邢方如.大豆蛋白基胶黏剂/胶膜增强与抗菌机制研究[D].北京:北京林业大学,2017.
[4] GU W D,LI F,LIU X R,et al.Borate chemistry inspired by cell walls converts soy protein into high-strength,antibacterial,flame-retardant adhesive[J].Green Chemistry,2020,22(4):1319-1328.
[5] LI W P,CHEN M S,LI Y C,et al.Improving mildew resistance of soy meal by nano-Ag/TiO2,zinc pyrithione and 4-cumylphenol[J].Polymers,2020,12(1):169.
[6] XING F R,CHEN H,ZHANG S F,et al.Effect of p-cumylphenol on the mold resistance of modified soybean flour adhesive and poplar plywood[J].Bioresources,2015,10(1):1543-1552.
[7] XU C J,XU Y C,CHEN M S,et al.Soy protein adhesive with bio-based epoxidized daidzein for high strength and mildew resistance[J].Chemical Engineering Journal,2020,390:124622.
[8] 董雅丽,郑环宇,赵影,等.不同抑菌剂对大豆蛋白胶粘剂防腐性能的比较研究[J].中国胶粘剂,2012,21(1):10-14.
[9] GU W D,LIU X R,YE Q Q,et al.Bio-inspired co-deposition strategy of aramid fibers to improve performance of soy protein isolate-based adhesive[J].Industrial Crops and Products,2020,150:112424.
[10] 李晓文,蒋明亮.三唑杀菌剂在木材保护中的应用和发展展望[J].林业科技通讯,2016(12):61-65.
[11] WANG Z T,CHEN Y,CHEN S Q,et al.Preparation and characterization of a soy protein based bio-adhesive crosslinked by waterborne epoxy resin and polyacrylamide[J].RSC Advances,2019,9(60):35273-35279.
[12] SINGH K B,DEVI A L,SINGH M D.Synthesis and stereochemistry of some sterically crowded triazolyl hydrazones[J].Indian Journal of Heterocyclic Chemistry,2008,18(2):165-168.
[13] BHAT M,NAGARAJA G K,KAYARMAR R,et al.Design,synthesis and characterization of new 1,2,3-triazolyl pyrazole derivatives as potential antimicrobial agents via a Vilsmeier-Haack reaction approach[J].RSC Advances,2016,6(64):59375-59388.
[14] 郝秀,范东斌.环氧单体交联改性大豆蛋白胶黏剂的研究[J].木材加工机械,2018,29(5):26-29.

备注/Memo

备注/Memo:
收稿日期:2020-09-20;改回日期:2020-10-15。
基金项目:浙江省与中国林业科学研究院省院合作项目(2018SY02)。
作者简介:陈欢(1997-),男,硕士研究生,从事环保胶黏剂研究。Email:chhh@caf.ac.cn。
通讯作者:杨昇(1989-),男,助理研究员,博士,从事木材胶黏剂研究。Email:Yangsheng@criwi.org.cn。
更新日期/Last Update: 1900-01-01